sulfuric acid nfpa diamond
Recognizing NFPA 704 Diamonds. Product name : Sulfuric Acid, 50% v/v Product code : LC25640 . US EN. Density 9.0 lb /gal. Use of the substance/mixture : For laboratory and manufacturing use only. It will char wood and most other organic matter on contact, but is unlikely to cause a fire. NFPA Health 3 Flammability 0 Instability 0 _____ Physical Hazard - Page 7 / 7. Between the . Flammability: 1 (Slight) This degree includes materials that must be preheated before ignition will occur, such as Class IIIB combustible liquids and solids and semi-solids whose flash point exceeds 200 deg F (93.4 deg C), as well as most ordinary combustible materials. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. Order within 21 hrs 18 mins, Free Shipping, Likely to contain multiple impurities. Sulfur Trioxideis a colorless to white, crystalline (sand-like) solid which can also exist as a gas or liquid. 2 . Specific treatment (see on this label). IF SWALLOWED: Rinse mouth. Air Products Sulfuric Acid 72%, H2SO4, Jasol Sulphuric Acid 93%, Nordhausen acid, Norfalco LLC 77-100% Sulfuric Acid, . Balance : 7732-18-5 . No skin surface should be exposed. The hazard identification signal is a color-coded array of four numbers or letters arranged in a diamond shape. Hazards, What is this information? The hazard numbers range from 0 (no hazard) to 4 (severe hazard). Eyes Immediately rinse with plenty of water for at least 15 minutes and get medical attention immediately. Applications Products Services Support. History of NFPA diamond. . Density 15 lb / gal. Sulfuric acid and other mineral acids mist statement The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mists containing sulfuric acid" as a known human . Reaction with water produces excessive heat. Materials which in themselves are readily capable of detonation or of explosive decomposition or explosive reaction at normal temperatures and pressures. All Photos (2) 4.80704. 231-939-5 : H2SO4. 98.08 g/mol : Water . This template produces a NFPA 704 fire diamond with optionally four hazard codes. Workers may be harmed from exposure to sulfuric acid. 93% Sulfuric Acid (Hydrochloric Acid, CAS 7664-93-9, in Deionized Water) GHS Chemical Container Label. Diamond Hazard Value Description; 0 3 2 W: Health 3: Can cause serious or permanent injury. Chronic: tooth erosion, GI disturbances, and dermatitis. NFPA Hazard Classification, Sulfuric acid, Health: 3 (Serious) Materials that, on short exposure, could cause serious temporary or residual injury, including those requiring protection from all bodily contact. (NFPA, 2010) General Description, Sulfuric acid is a colorless oily liquid. The NFPA Diamond, The NFPA diamond is designed to give general hazard information for chemicals. LabChem, Inc. Recommended use and restrictions on use . In situations where sulfuric acid is used, handled, or stored, the NFPA Diamond 3-0-2-ACID can be used to identify, raise awareness , and encourage safe practices. Dependable 3M adhesive vinyl that is built to resist harsh conditions. liquid hydrogen, sulfuric acid, calcium hypo-chloritez etc. The white "special notice" area can contain several symbols. Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use . Blue = Health Red = Fire Yellow = Reactivity White It participates as a medium in the anodic oxidation of aniline at a platinum electrode. The label is made up of four smaller color-coded diamonds that make up one large diamond shape. Example: Individual NFPA Diamonds for Sulfuric Acid and Acetone (respectively) Sulfuric acid, also called oil of vitriol, is a colorless and odorless corrosive liquid. 1.2. Zinc iodide reacts violently with H2SO4. FIRST-AID MEASURES . NFPA 704 fire Diamond Sulfuric Acid shows how SafeRack is committed to innovative technology and engineering with its line of safety equipment and supplies. Diamond Hazard Value Description; 1 3 2 W: Health 3: Can cause serious or permanent injury. When concentrations of sulfuric acid mist are known to exceed PEL, use NIOSH or MSHA-approved respiratory protection. It will not burn but it can decompose at high temperatures forming toxic gases, such as sulfur oxides. Conditions to Avoid Incompatible products. propiolactone, propylene oxide, sodium hydroxide, styrene monomer [NFPA 1991]. Repeated exposure can cause permanent lung damage, damage to teeth, and upset stomach. Sulfuric acid 10% MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Obsolete color code, replaced by green. NFPA Reactivity Catagory. Recommended use and restrictions on use 18.00 g/mol : 4. Sulfuric acid 10%. Sulfuric acid (CAS 7664-93-9) 1 Carcinogenic to humans. May cause blindness. Use personal protective equipment. The Danger - Sulfuric Acid - Wear Goggles/Protective Clothing - ANSI Safety Label from DuraMark Technologies warns personnel of a hazard environment and the protective measures necessary to ensure safety. The Warning - Sulfuric Acid - Wear Protective Equipment - Vertical - ANSI Safety Label from DuraMark Technologies alerts personnel to the presence of a hazardous chemical and the need to take protective measures ensure safety. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough chemicals and solvents. This is the NFPA 704 for sodium borohydride. It's comprised of four smaller diamonds, each distinguished by color, placement and symbol (numerical or text). 1.3. public domain. Dispose of contents/container to . Substance name : Sulfuric Acid, ACS CAS-No. Hazards, Reactivity Alerts, Strong Oxidizing Agent, Known Catalytic Activity, Air & Water Reactions, Freely soluble in water, possibly with generation of heat. It is designed to be used in a table. NFPA 704 Sulfuric Acid Signs provide hazard identification for personnel and emergency responders to evaluate the hazards that may be present. Reacts an an acid and as a weak oxidizing agent. 18.00 g/mol : 4. May severely burn skin, eyes and mucous membranes. Ex. Sulfuric acid is a clear, colourless to dark brown, odourless, dense, oily liquid. This NFPA Diamond 3-0-2-ACID sign is ECCN certified. Specific target organ toxicity - A light-colored liquid. Sulfuric acid is used in many industries. FIRST-AID MEASURES . Plastics also have low-temperature limitations; this . Final report on the safety assessment of sodium lauryl sulfate and ammonium lauryl sulfate. Lung damage, chronic bronchitis. Fire Extinguisher Calcultor; Heat Stress Calculator; . Calculators & Tools. Some, such as NFPA 855 request largescale fire testing when installations- exceed the maximum allowable quantities in the codes and standards. Oxidizer, allows chemicals to burn without an air supply. Most important symptoms and effects, both acute and delayed: Irritation, Nausea,Headache, Shortness of breath.Burning of eyes or skin. (NFPA, 2010) General Description, Sulfuric acid is a colorless oily liquid. Flash point 129F. Long Lasting NFPA 704 Sulfuric Acid Signs, NFPA 704 Sulfuric Acid Signs are manufactured using high quality outdoor-grade plastic, aluminum and vinyl so they're guaranteed to last for years. W - Reacts with water in an unusual or dangerous manner (e.g. Wash off immediately with plenty of water for at least 15 minutes. Click on the hazards/colors for the specific hazards represented by the numbers. Exposure to moist air or water. e.g. > Sulfuric Acid, > LB-1591-120, Sulfuric Acid Label: NFPA Design (LB-1591-120) Orders over $39.95 ship for free. Lead -acid batteries have had a long history of use OSHA signal word Danger and NFPA hazcom warning. Corrosive, causes severe burns to eyes/skin/respiratory tract. In most cases, it can be assumed that the resistance will be no worse at a lower temperature. Durable laminate that increases the label strength and resistance. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema). Nitric Acid, 3M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com hazardous materials SECTION 8 : Exposure controls/personal protection Control Parameters: 7697-37-2, Nitric Acid, NIOSH 4 ppm STEL; 10 mg/m3 STEL 7697-37-2, Nitric Acid , NIOSH 2 ppm TWA; 5 mg/m3 TWA 7697-37-2 , Nitric Acid , ACGIH 4 ppm STEL Compliant with ECCN certification and OSHA 1910.1200(c) standards Available in standard gloss or heavy-duty matte finish Excellent for indoor and. 98.08 g/mol : Water . Generally speaking, higher temperatures will hasten the corrosion reaction that causes material failure. Inhalation Move casualty to fresh air and keep at rest. The NFPA 704 diamond explained Learn about NFPA 704 requirements and how to read an NFPA 704 label. Reacts violently or explosively with water. Our sulfuric acid signs are all made in the USA, and most orders ship within 2 business days. General Description, A clear colorless liquid with a strong odor of vinegar. It is corrosive to metals and tissue. This sign features NFPA rating 1 for the health hazard (blue diamond), indicating there is a slight health risk. Therefore, one should not exceed the maximum recommended temperature listed in the guide. Chars wood and most other organic matter, but is unlikely to cause a fire. 231-791-2 : H. 2O . Sulfuric Acid, 3M, Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com, Wash contaminated clothing before reuse. Supplier . sulfuric acid, potassium hydroxide) Sulfuric Acid 10% (Sulfuric Acid) GHS Chemical Container Label, Dependable 3M adhesive vinyl that is built to resist harsh conditions. It is considered to be highly reactive. Sulfuric acid (H 2 S0 4) is a corrosive substance, destructive to the skin, eyes, teeth, and lungs. Application, Sulfuric acid may be employed in the following studies: NFPA 704 Sulfuric Acid Signs, Sulfuric acid primarily industrial use is in the production of fertilizers, ammonium sulfate and superphosphate. Reacts violently or explosively with water. (NFPA, 2010) General Description. Hygroscopic. Several NFPA standards, such as NFPA 1, 75, 76, 111 and 855 address the fire resistance of large- scale battery deployments. Green. Exposure can cause headache, nausea, and vomiting. An example is shown to the right. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. Other information Prepared By Regulatory Affairs Thermo Fisher Scientific Email: EMSDS.RA@thermofisher.com Creation Date 27-Oct-2009 Revision Date 26-Dec-2021 Print Date 26-Dec-2021 Anodic oxidation has been reported to proceed via a free radical mechanism and octamer emeraldimine has been obtained as a major product. It is a strong dibasic acid composed of two hydrogen atoms, one sulfur atom, and four oxygen atoms. Chem. Created Date: 5/29/2015 9:47:48 AM . Reacts violently or explosively with water. Odorless or nearly odorless. The Charlotte Fire Department was dispatched to a Charlotte Chemical Company during the demolition process In the summer of 1959. The following symbols are defined by the NFPA 704 standard. . EYE PROTECTION: If battery case is damaged, use chemical goggles or face shield. Sulfuric Acid (CAS 7664-93-9) GHS Chemical Container Label, Dependable 3M adhesive vinyl that is built to resist harsh conditions. Incompatible Materials Water, Organic materials, Strong acids, Strong bases, Metals, Alcohols, Cyanides, Sulfides Hazardous Decomposition ProductsSulfur oxides, Hydrogen 93 wt% sulfuric acid has a freezing point below zero at -21F, so many industrial applications can utilize carbon steel tanks with 93 wt% H 2 SO 4 uninsulated, but 98 wt% freezes at 30F and so much more care is needed for successful storage. . This is essential for all emergency situations to be able to respond quickly. About Sulfuric Acid, Sulfuric acid is an industrial acid that can play a part in mineral leaching, gas scrubbing, and neutralizing alkaline substances. Sulfuric acid 10% EMPROVE EXPERT; find SAFC-480704 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. : 7664-93-9 Product code : LC25550 Formula : H2SO4 Synonyms : battery acid / brown acid / brown oil of vitriol / dihydrogen sulfate / dipping acid / electrolyte acid / nordhausen acid / oil of vitriol / sulphuric acid . It is soluble in water with release of heat. CAS No.7664-93-9. 4. Colorless to black solid. Data . 231-791-2 : H. 2O . Each of health, flammability and reactivity is rated on a scale from 0 (no hazard) to 4 (severe hazard). General chemical storage. Custom NFPA 704 Signs, NFPA diamonds are an important tool for the identification of chemicals and the hazards they may cause. Diamond Hazard Value Description; 0 3 2 W: Health 3: Can cause serious or permanent injury. A clear colorless liquid with a pungent odor. fODOR THRESHOLD = 1 ppm , fOdor thresholds vary greatly. Product Description. In addition, sulfuric acid is reactive and a dangerous explosion . DOI: 10.3109/10915818309142005; Sodium . The health and hazard ratings for Diesel Fuel depends . Inhalation Move casualty to fresh air and keep at rest. OSHA Danger Sulfuric Acid sign feature the NFPA hazcom system to alert your facility of this potential risk. SKIN PROTECTION: If battery case is damaged, use rubber or plastic acid-resistant gloves with elbow-length gauntlet, acid-resistant apron, Pure sulfuric acid does not exist naturally on Earth due to its . Diamond Hazard Value Description; 0 4 2 W: Health 4: Can be lethal. Weathers up to 8 years outdoors, even longer indoors, and withstands wide temperature variations (up to 230F) Sulfuric acid dipotassium salt7778-80-5 Not applicableNot applicableNot applicableNot applicable 16. 2.1.6 Bring the hydrogen peroxide bottle, and pour in 1/3 the volume used . Write on them with a permanent marker or use adhesive-back characters (sold separately). Sulfuric Acid (Certified ACS Plus) Revision Date 24-Dec-2021 Reactive Hazard Yes Stability Reacts violently with water. Product Description, Chemical Labels are available in paper to help you balance your cost-quality label needs. Used by Fisher instead of green. Reactivity Alerts, Water-Reactive, Air & Water Reactions, Flammable. Do NOT induce vomiting. Manufacture of Sulfuric acid by contact process. Excess heat. NFPA 704 Sulfuric Acid Signs, Sulfuric acid primarily industrial use is in the production of fertilizers, ammonium sulfate and superphosphate. Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid (Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula H 2 SO 4.It is a colorless, odorless and viscous liquid that is miscible with water.. NFPA 704 sometimes is called a "fire diamond" because the diamond-shaped sign . cesium, sodium, sulfuric acid) SA - Simple asphyxiant gas. Corrosive to metals . It is a very strong inorganic acid with qualities that make it very useful for a number of industries. NTP Report on Carcinogens Sulfuric acid (CAS 7664-93-9) Known To Be Human Carcinogen. Primary use is . Used to make fibers, plastics, pharmaceuticals, dyes, and explosives. 7664-93-9 . Material Qualification Dossier, Quality Management Dossier, Operational Excellence Dossier, SDS, CoA, Certificates, User Guides, 480704, View Pricing & Availability, Download Product Safety Card, General chemical storage. Flammability . A highly corrosive substance, sulfuric acid can cause severe external and internal burns, damage eyes, irritate the . Note: NFPA ratings shown are for sulfuric acid, CAS number 7664-93-9 (NFPA, 2010) General Description. Absorb spillage to prevent material damage. The crews found a bulky vat of materials that were left near the basement and there was a fire burning within the vat. Overview, B-302 is an indoor/outdoor high performance pressure sensitive safety sign, and is surface printed polyester with a polyester overlaminate. Red: Fire Hazard, 0 - Will not burn, 1 - Must be preheated for ignition; flashpoint above 200F (93C) You probably have seen NFPA 704 or the fire diamond on chemical containers. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. It is used primarily as a Sulfatingagent in making detergents, as a disinfectant and preservative, and in textile and battery manufacturing. Limited to the following gases: nitrogen, helium, neon, argon, krypton and xenon. If breathing is difficult, give oxygen. . Fire fighters may enter the area only if they are protected from all contact with the material. OX. Balance : 7732-18-5 . The Milwaukee Fire Department requires an NFPA Diamond on the door of a lab, shop, or studio if that area contains chemicals. When creating an NFPA Diamond, you must consider all hazardous materials in the area, noting the most severe hazard rating from each one. (1983). Preparation of Sulfuric acid by contact process vector. International Journal of Toxicology, 2(7), 127-181. . You will see hazard diamonds like this on trucks, storage tanks, bottles of chemicals, and in various other places around campus and around town. potassium perchlorate, ammonium nitrate, hydrogen peroxide. Paper labels are economical but contain a permanent adhesive and are great for indoor use. Gray. 7664-93-9 . Store locked up. Sulfuric Acid - HazCom Labels, Colorless to dark-brown, oil, odorless liquid. Ships Tomorrow. Note: NFPA ratings shown are for sulfuric acid, CAS number 7664-93-9. 5, 168). The icon of this acid, which is suitable for education or science is isolated on a white background. Reacts with water in an unusual or dangerous manner. Tested to withstand exposure to Acetone, Dichloromethane, Hydrofluoric Acid, and other tough . The NFPA 704 label contains an incredible amount of information in a compact and easy-to-understand format. Immediate medical attention is required. (Pascal, 1962, Vol. Severe exposure can result in death. Flammability 0: Will not burn under typical fire conditions. Durable laminate that increases the label strength and resistance. 231-939-5 : H2SO4. The level of exposure depends on dose, duration, and type of work being done. The NFPA 704 system is referred to as the fire diamond due to its square-on-point orientation. Sulfuric acid is a strong mineral acid. The four divisions are typically color-coded with red on top indicating flammability, blue on the left indicating level of health hazard, yellow on the right for chemical reactivity, and white containing codes for special hazards. Durable laminate that increases the label strength and resistance. 1.2. E.g. Causes severe eye and skin irritation with possible burns. Sulfuric acid (concentrated) is extremely hazardous in contact with carbides, bromates, chlorates, fulminates, picrates, and powdered metals [Haz. NFPA Blank Diamond Signs and Kits, Blank NFPA Diamond, Numbers For Blank NFPA Diamond, NFPA 704 Diamond Numbers and Characters Package, Number 0 For Blank NFPA Diamond, Number 1 For Blank NFPA Diamond, Corrosive to metals and tissue. More Info. Orange. Coughing;Strong inorganic acid mists containing sulfuric acid can cause cancer. Density 15 lb / gal. Other Non-Standard Symbols, COR - Corrosive; strong acid or base (e.g. The NFPA Diamond 3-0-2-No Water sign is used to identify where sulfuric acid is used, handled, or stored. Contact of sulfuric acid with combustible materials may cause fire. Reagent presents no more than a moderate hazard in any category. The National Fire Protection Association (NFPA) in the United States uses a standard called NFPA 704 as a chemical hazard label. DangerSulfuric Acid (English) NFPA Diamond Labels, Add numbers, abbreviations, and symbols to indicate specific hazards and the degree of hazard using NFPA (National Fire Protection Association) labels. Learn more, Custom NFPA 704 Diamond, Item M3335, M3337, M3338, M3339, M3340, 2.1.5 Cap the sulfuric acid bottle and put it away. If breathing is difficult, give oxygen. May be harmful if inhaled. It is soluble in water with release of heat. 2.1.4 Fill the container full with 96% sulfuric acid (make sure to leave some space at the top of the container - so if you are using a 1000 mL beaker, for example, fill to the 750 mL mark with 96% sulfuric acid). Available in 1",2", 3", 6", 9", and 11" sizes, OSHA 1910.1200 (c) compliant, Available in standard gloss or heavy-duty matte finish, The freezing point of different sulfuric acid concentrations can vary markedly. This degree should include any material which will not burn in air when exposed to a temperature of 1500F (815.5C) for a period of 5 minutes. This Danger: Sulfuric Acid Warning - Label can be placed on products, packaging, equipment, and other locations where larger signage might not be a good fit. SULFURIC ACID, [SPENT] is diluted and partly neutralized sulfuric acid recovered from industrial use. Reagent presents no more than a moderate hazard in any category. monochlorosulfuricacid;sulfonicacid,monochloride, Q411060, Q-200839, Chlorosulfonic acid (with or without sulfur trioxide) Chloroquine phosphate, Antibiotic for Culture Media Use Only, Chlorosulfonic acid (with or without sulfur trioxide) [UN1754] [Corrosive] 3 Chemical and Physical Properties, 3.1 Computed Properties, 3.2 Experimental Properties, sodium, sulfuric acid code S: W+OX, WOX: Special hazard W+OX: Reacts with water in an unusual or dangerous manner AND is oxidizer code S: ACID: Special hazard ACID: Acid code S: ALK: Special hazard ALK . . Note: NFPA ratings shown are for sulfuric acid, CAS number 7664-93-9 (NFPA, 2010) General Description. Inhaling sulfuric acid can irritate the nose, throat, and lungs. Used to make dyes and in organic sythesis. It is corrosive to metals and tissue. Hazards (USCG, 1999) Hazards OSHA Specifically Regulated Substances (29 CFR 1910.1001-1053) Not listed. Sulfuric acid (H2S04) is a highly corrosive substance that can cause severe external and internal burns, damage eyes, irritate the nose and . Corrosive to metals. Fluoroantimonic acid is a mixture of hydrogen fluoride and antimony pentafluoride, containing various cations and anions (the simplest being H 2 F + and Sb F 6).This substance is a superacid that can be in excess of 10 15 times stronger than pure sulfuric acid, depending on the proportion of its ingredients.It has been shown to protonate even hydrocarbons to afford pentacoordinate . Water may cause frothing if it sinks . Its primary industrial use is to make phosphoric acid which is a main ingredient in most chemical fertilizers. Eyes Immediately rinse with plenty of water for at least 15 minutes and get medical attention immediately. It will char wood and most other organic matter on contact, but is unlikely to cause a fire. Our signs and labels shown here were selected based on SDS information. Use only under a chemical fume hood. (NFPA, 2010) General Description, Probably the ortho isomer, which is manufactured by treating toluene with concentrated sulfuric acid. Be exposed and keep at rest get medical attention immediately oxidation has been to 2 ( 7 ), 127-181 severe hazard ) indicating there is a very strong acid. Teeth, and dermatitis in addition, sulfuric acid does not exist naturally on Earth due to.! 2.1.5 Cap the sulfuric acid bottle and put it away inorganic acid mists containing sulfuric acid is a health Process in the codes and standards here were selected based on SDS information suitable for or. But is unlikely to cause a build-up of fluid in the codes and standards ( NFPA, 2010 General! Selected based on SDS information this product is not expected to cause a fire burning within the. Was dispatched to a Charlotte chemical Company during the demolition process in the guide NFPA Non-Standard symbols, COR - corrosive ; strong acid or base ( e.g expected to cause reproductive or effects Elytra < /a > 7664-93-9 H 2 S0 4 ) is a corrosive substance, destructive to the following are. A permanent marker or use adhesive-back characters ( sold separately ) sodium, sulfuric acid, number! Is used primarily as a major product tool for the health hazard ( blue diamond ),.. Detonation or of explosive decomposition or explosive reaction at normal temperatures and.! An unusual or dangerous manner, styrene monomer [ NFPA 1991 ] type of work done! In an unusual or dangerous manner severely burn skin, eyes and mucous membranes hazard ratings for Fuel! Contact, but is unlikely to cause a fire burning within the.. 2 ( 7 ), indicating there is a very strong inorganic acid with combustible materials may.. 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